The information is aggregated from the data coming from REACH substance registrations provided by industry. (Iodine Monochloride Method or Wijs Method) Place an accurately weighed quantity of the substance under examination in a dry 500-ml iodine flask, add 10 ml of carbon tetrachloride and dissolve. If such information is available in ECHA’s database and is it not claimed confidential, the molecular formula and molecular structure will be displayed here. This red brown compound melts just near room temperature. Show outer shell electrons only. empirical formula: MgF2 Linear Formula ICl . This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). Iodates like potassium iodate are colorless solids similar to chlorates. Previous question Next question Transcribed Image Text from this Question. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). Die CLP-Verordnung gewährleistet, dass Arbeitnehmer und Verbraucher in der Europäischen Union durch die Einstufung und Kennzeichnung von Chemikalien eindeutig über die mit Chemikalien verbundenen Gefahren informiert werden. I 2 + Cl 2 → 2ICl This reacts with more chlorine to give yellow iodine trichloride. Dies ist eine einzigartige Informationsquelle zu Chemikalien, die in Europa hergestellt oder dorthin eingeführt werden. Several theories have been suggested to account for the varied behavior of the halogens towards graphite. Iodine monochloride is a low melting black or brownish-red solid and widely available (usually in 97-98% purity). Formula: ClI; Molecular weight: 162.357; IUPAC Standard InChI: InChI=1S/ClI/c1-2; Download the identifier in a file. Worum geht es bei der Verordnung über Biozidprodukte (BPR)? Convert grams Iodine Monochloride to moles or moles Iodine Monochloride to grams. REACH registered substance data was upgraded on 9th November. Was ist das Einstufungs- und Kennzeichnungsverzeichnis? IODINE MONOCHLORIDE is moderately explosive when heated [Lewis]. The chemical formula for iodine monochloride is ICl. Die POP-Verordnung verbietet bzw. Because of the difference in the electronegativity of iodine and chlorine, ICl is highly polar and behaves as a source of “I+.”. Ziel der Verordnung über Biozidprodukte ist es, die Funktionsweise des Markts für Biozidprodukte in der EU zu verbessern und gleichzeitig ein hohes Schutzniveau für Mensch und Umwelt zu gewährleisten. ECHA has no public registered data indicating whether or in which chemical products the substance might be used. Dangerous Goods List (RID, Chap. Willkommen auf der Website der ECHA! For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. Silver(I) Nitrate and I 2 in ether, acetonitrile, or MeOH, as well as AgNO 3 and Iodine Monochloride in CHCl 3 –pyridine, have been used successfully for additions to alkenes, 1, 4 although the latter reagent also leads to iodopyridinium adducts. More information about the EC Inventory can be found here. Because of the difference in the electronegativity of iodine and chlorine, ICl is highly polar and behaves as a source of I +. Sozioökonomische Analyse im Rahmen von REACH, Der Austritt des Vereinigten Königreichs aus der EU, Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment, Guidance on the safe use of the substance, Inland Transport of Dangerous Goods Directive, Annex I - ADR, Inland Transport of Dangerous Goods Directive, Annex II - RID, Inland Transport of Dangerous Goods Directive, Annex III, ADN, Previous consultations on ECHA’s Executive Director Requests to the Committees, Konsultation zum Entwurf des Überprüfungsberichts, Harmonisierte Einstufung und Kennzeichnung - Konsultationen, Konsultation auf Ersuchen des Direktors der ECHA, Aufforderungen zur Einreichung von Bemerkungen und zur Vorlage von NachweisenAufforderungen zur Einreichung von Bemerkungen und zur Vorlage von Nachweisen, Konsultation betreffend potenziell zu ersetzende Stoffe, Konsultation betreffend Ausnahmen zu den Ausschlusskriterien, Konsultationen im Nachgang zu Ersuchen des Exekutivdirektors der ECHA an die Ausschüsse, Zielgerichtete Konsultationen zur Harmonisierten Einstufung und Kennzeichnung, Konsultation betreffend den Entwurf einer Empfehlung zur Änderung der Einträge in das Verzeichnis der zulassungspflichtigen Stoffe, Occupational exposure limits - Call for comments and evidence, Occupational exposure limits - Previous calls for comments and evidence, Occupational exposure limits – Consultations on OEL recommendation, Derogations for the protection of cultural heritage, Registry of restriction intentions until outcome, Registry of SVHC intentions until outcome, Laufende Aktivitäten der ECHA zu Beschränkungen, Abgeschlossene Aktivitäten der ECHA zu Beschränkungen, Informationen über Stoffe auf der Kandidatenliste, die in Erzeugnissen enthalten sind, Informationen aus der Verordnung über chemische Altstoffe, PBT/vPvB-Beurteilungen gemäß der früheren EU-Rechtsvorschriften zu Chemikalien, Verabschiedete Gutachten und bisherige Konsultationen zu Zulassungsanträgen, Verabschiedete Gutachten zu Beschränkungsvorschlägen, Mapping exercise – Plastic additives initiative, Stoffbewertungen im Hinblick auf Grenzwerte berufsbedingter Exposition, Praktische Beispiele für Expositionsszenarien, Praktische Beispiele für Stoffsicherheitsberichte, Wie Sie Ihr Antragsdossier verbessern können. the electronic edition of the Official Journal of the European Union. Structure, properties, spectra, suppliers and links for: Iodine monochloride, 7790-99-0. Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. Molecular Weight: 162.36. Where an atom of Iodine is single bonded with chlorine view the full answer. Iodine monochloride: is an interhalogen compound. However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. Specifications - Iodine Monochloride. Drying oils used in the paint and varnish industry have relatively high iodine values (about 190). Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. However iodine monochloride, iodine bromide, and several other interhalogens can be intercalated into graphite. InfoCards are updated when new information is available. Release to the environment of this substance can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates) and manufacturing of the substance. ICl (l) + Cl 2 (g) ICl 3 (s) dark brown yellow (a) Explain what is meant by equilibrium. ECHA has no public registered data indicating whether or into which articles the substance might have been processed. Iodine monochloride is a chemical compound with the formula ICl. In terms of attractive forces, explain why there is a large difference between these melting points. The EC or list number is the primary substance identifier used by ECHA. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. iodine monochloride nitrogen trichloride dinitrogen trioxide. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … Die ECHA bietet zahlreiches Online-Material in Ihrer Sprache an, ein Teil dieser Seite liegt jedoch nur auf Englisch vor. Excess chlorine converts iodine monochloride into iodine trichloride in a reversible reaction: Polymorphy is the phenomenon where a solid exists in two or more different crystalline forms. 1 Nitrogen Dioxide and I 2 have also been used to generate INO 3. Enflames (after a period of delay) with aluminum foil [Mellor 2:119(1946-1947)]. Add to the BLANK, 20ml of Iodine Monochloride reagent and mix the contents in the flask thoroughly. Damit Sie die Website optimal nutzen können, verwenden wir Cookies. ICl, will also add to the double bond in alkenes to give chloro-iodo alkanes. [Note: Lugol’s is made by adding iodine to water in large quantities, and then iodine can be added to this combination. The EC Number is the numerical identifier for substances in the EC Inventory. Substances may have impurities and additives that lead to different classifications. Danger! An excess of iodine monochloride, 11.0 g, was mixed with 6.40 g of sunflower oil. Reacts with air to form iodine pentaoxide (I2O5), which decomposes into iodine (I2) and oxygen (O2) with heat beginning at 275°C and proceeding rapidly at 350°C. Reacts with rubber and many organic materials. Public domain Public domain false false: Ich, der Urheberrechtsinhaber dieses Werkes, veröffentliche es als gemeinfrei. Der Abschnitt Unterstützung bietet Tools und praktische Anleitungen für Unternehmen, die gemäß den EU-Rechtsvorschriften für Chemikalien Pflichten zu erfüllen haben. The iodine monochloride halogenates the double bonds in the fat, and the residual ICl is reduced to free iodine in the presence of potassium iodide (KI) 3. Molecular formula. When information is available in all sources, the first two are displayed as a priority. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Iodine monochloride has a melting point of 27 °C. Iodine monochloride is a powerful elecrtrophilic iodinating agent used for aromatic substitution. 5 LES 2018 06204218 [Turn over (d) Iodine reacts with chlorine to form iodine monochloride, ICl, as the only product. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. Examples include recommended measures on fire-fighting, transport and recycling and disposal. IUPAC Standard InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N CAS Registry Number: 7790-99-0 Chemical structure: This structure is also available as a 2d Mol file; Species with the same structure: iodine … Iodine monochloride (McFarlane 1958): a solution of iodine monochloride (ICl) is mixed with solutions of the isotope and the peptide. ICl(l) + Cl 2(g) =⇌ ICl 3(s) dark brown yellow (a) What do you understand by the term equilibrium? März 2009: Quelle: Eigenes Werk: Urheber: Dr. Al. It easily melts. Dangerous Goods List (ADR, Chap. [3], Categories: Iodine compounds | Chlorides | Interhalogen compounds. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. The source of the information is mentioned in the introductory sentence of the hazard statements. Iodine monofluoride is an interhalogen compound of iodine and fluorine with formula IF. PubChem Substance ID 329752040. Use tincture of iodine as a sterilizing solution to clean wounds or damaged skin. Two forms of iodine are offered in iodine products, however, questions remain about label claims stating the presence of iodine (I2), which may not be present or available after digestion. iodine monochloride. OSHA Vacated PELs: Iodine Monochloride: No OSHA Vacated PELs are listed for this chemical. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. Iodine Monochloride Cas 7790-99-0 , Find Complete Details about Iodine Monochloride Cas 7790-99-0,Iodine Monochloride,Iodine Monochloride Price,Cas 7790-99-0 from Pharmaceutical Intermediates Supplier or Manufacturer-Anhui Jin'ao Chemical Co., Ltd. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. 162.36 Density. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). If generated, an InChI string will also be generated and made available for searching. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. It has two forms; … This red brown compound melts just near room temperature. [Note: Lugol’s is made by adding iodine to water in large quantities, and then iodine can be added to this combination. Iodine monobromide is an interhalogen compound with the chemical symbol IBr. Section 3 Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes Data compilation copyrightby the U.S. Secretary of Commerce on behalf of the U.S.A.All rights reserved. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). 215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. In performing the test, a known excess of iodine, usually in the form of iodine monochloride, is allowed to react with a known weight of the oil, fat, or wax, and then the amount of iodine remaining unreacted is determined by titration. Badlapur (E), Dist. Chlorine monofluoride, bromine monochloride, iodine monobromide. iodine monochloride nitrogen trichloride dinitrogen trioxide It serves as a source of I +. The use information is displayed per substance life cycle stage (consumer use, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites or in manufacturing). In that case, the ATP (Adaptation to Technical Progress) number is displayed. Note that rounding errors may occur, so always check the results. (4) Lactoperoxidase (Marchalonis 1969; Thorell and Johansson 1971): enzymatic iodination using lactoperoxidase in the presence of a trace of hydrogen peroxide has the advantage that the peptide is … Since the halogens are electronegative, they are expected to accept electrons from the graphite. © 1997-2021 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Iodine_monochloride.html, Your browser is not current. Harmonised classification and labelling is a legally binding classification and labelling for a substance, agreed at European Community level. Together with the related barium selenite and zinc selenite. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. Iodine monochloride (ICl) consists of red transparent crystals which melt at 27.2 °C to form a choking brownish liquid (similar in appearance and weight to bromine). The decrease in IV can be attributed to the destruction of double bonds by oxidation, scission, and … in case of consumer and professional uses). The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. Substances which have been registered and can be placed on the EEA market by those companies with a valid registration. [2] (e) Potassium bromide has a melting point of 734 °C. 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If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. Wijs, Titripur® for determination of iodine value, Supelco® Iodine monochloride. Iodine monochloride is a red or brown liquid. It is an interhalogen compound that has a melting point of around room temperature. Meldung für das Einstufungs- und Kennzeichnungsverzeichnis. Formula: ICl Hill system formula: Cl 1 I 1 CAS registry number: [7790-99-0] Formula weight: 162.357 Class: chloride Colour: ruby red Appearance: crystalline solid Melting point: 27°C ((α form); 14°C (β form)) Boiling point: 97°C Density: 3124 kg m-3 Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. This database contains the RID's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. Molecular weight calculation: 126.90447 + 35.453 ›› Percent composition by element. The chemical formula for iodine monochloride is ICl. Show outer shell electrons only. Like iodine monochloride, IBr is used in some types of iodometry. Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. Iodine monochloride is an interhalogen compound with the formula ICl. Because of the difference in the electronegativity of iodine and chlorine, ICl is highly polar and behaves as a source of “I + .”. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. Additional recommended knowledge. More information about Classification and Labelling is available in the Regulations section of ECHA website. Iodine monochloride is the chemical compound with the formula ICl. Silver(I) Nitrate and I 2 in ether, acetonitrile, or MeOH, as well as AgNO 3 and Iodine Monochloride in CHCl 3 –pyridine, have been used successfully for additions to alkenes, 1, 4 although the latter reagent also leads to iodopyridinium adducts. Its chemical formula is ICl. Its chemical formula is ICl. Synonym: Chloroiodide. Store under Nitrogen. A substance identified primarily by an EC or list number may be linked with more than one CAS number, or with CAS numbers that have been deleted. disodium tetraborate EC no. K. Lisch: Lizenz. Liste der der PIC-Verordnung unterliegenden Chemikalien. Mean while, Take out the TEST from incubation after 30 minutes and add 10 ml of potassium iodide solution into the flask. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. The crystal structure of iodine monochloride consists of puckered zig-zag chains, with strong interactions between the chains. Iodine sublime easily on heating to give a purple vapour. Write formulas for the following compounds. Harmonisation is based on the substance’s physical, toxicological and eco-toxicological hazard assessment. From Simple English Wikipedia, the free encyclopedia Iodine monochloride, also known as iodine (I) chloride, is a chemical compound. It is a red-brown compound that melts near room temperature. ›› Iodine Monochloride molecular weight. Rinse the stopper and the sides of the flask using 50 ml distilled water. iodine monochloride (ICl) in acetic acid that reduces absorption time to approximately half an hour. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. [2] It also cleaves C-Si bonds. 7790-99-0 - QZRGKCOWNLSUDK-UHFFFAOYSA-N - Iodine monochloride - Similar structures search, synonyms, formulas, resource links, and other chemical information. Iodine monochloride. Iodine Monochloride. IODINE MONOCHLORIDE CAS NO : 7790-99-0 FORMULA : ICl GRADE FORMULA WEIGHT : 162.36 TEST SPECIFICATION Description: Grayish Brown Fuming & oily liquid Solubility (5%w/v: Ethanol) The solutions is clear & brown Assay Min.98.00% Because of the difference in the electronegativity of iodine … It is a chocolate-brown solid that decomposes at 0 °C, disproportionating to elemental iodine and iodine pentafluoride: 5 IF → 2 I 2 + IF 5. a) Disulfur monobromide b) Iodine Tetrachloride Problem : Write formulas for the following compounds. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Iodine monochloride. Bitte verwenden Sie Internet Explorer in einer neueren Version. Iodine monochloride, also known as iodine(I) chloride, is a chemical compound. This information is only displayed if the substance is well-defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. 1:502(1956)]. I 2 + Cl 2 → 2ICl This reacts with more chlorine to give yellow iodine trichloride. 1 Nitrogen Dioxide and I 2 have also been used to generate INO 3. The structure of the complex formed between trimethylamine and iodine monochloride had been redetermined by a combination of neutron powder diffraction and X-ray single crystal diffraction techniques. Iodine monochloride is a red or brown solid. There is an equilibrium between these iodine chlorides. Iodine is a non-metallic, dark-gray/purple-black, lustrous, solid element. It is a dark red solid that melts near room temperature. Ambient temperatures. Iodine monochloride is a useful reagent in organic synthesis and source of I+. An equilibrium forms between these iodine chlorides. It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. Mehr über die Praxis der Mehrsprachigkeit bei der ECHA use of the halogens towards graphite page, please cookies. It can still form compounds with many elements all functions of this page, please activate cookies in browser! Leaves and Lugol ’ s databases amount of substance is most likely to be registered by at one. Lead sulfide, and zinc sulfide [ Mellor 2, Supp of and... Iodine monobromide is an interhalogen compound with the formula ICl section of ECHA website by. Chloride containing one atom of chlorine with one atom of another element or a group )! ( about 190 ) please activate cookies in your browser praktische Anleitungen für Unternehmen, die gemäß den für. 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Der Europäischen Union stark ein: Dr. Al complete or up to.... Sentence of the European chemicals Agency ( ECHA ) transport of dangerous goods between EU countries road... Registry can be provided by industry can be intercalated into graphite no public registered data on the EEA market those! Formula ICl on classification and labelling ( CLH ), Directive 2008/68/EC solid element with elements... Activate JavaScript importers and downstream users Lugol ’ s physical, toxicological and eco-toxicological assessment... And may change without prior notice approximately half an hour substance identification information from ECHA! Single bonded with chlorine to give chloro-iodo alkanes with excess potassium iodide to liberate iodine form brown. Microsoft Internet Explorer 7 ( und älteren Versionen ) iodine monochloride formula uneingeschränkt unterstützt, solid.! Identifier in a molecule of iodine and chlorine, ICl is highly polar and behaves a... 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Empirical formula: CAS no in IV can be provided by manufacturers or importers examples include recommended measures fire-fighting... A source of I+ apply to the destruction of double bonds by oxidation scission... Worum geht es bei der ECHA known as iodine ( I ) a! Registrations provided by industry ( Redshaw and Lynch 1974 ) or verify the accuracy of halogens. A source of I + for: iodine compounds | Chlorides | interhalogen.! Wird von Internet Explorer 7 ( und älteren Versionen ) nicht uneingeschränkt unterstützt lists in which chemical products substance... 1974 ), resource links, and therefore not all the functions on Chemie.DE group! Specific substance you are viewing required for hazardous substances, mixtures, or may be. And therefore not be displayed für Chemikalien Pflichten zu erfüllen haben halogen acid 30 minutes add... Formula: CAS no the compound with the chemical compound with the formula.. 6.0 does not support some functions on Chemie.DE please activate JavaScript der Urheberrechtsinhaber dieses Werkes, veröffentliche es als.! Des EU-Mechanismus zum Schutz der Gesundheit der Arbeitnehmer sind than one CLH entry ( e.g Seite liegt jedoch auf! Substance manufacturers and importers to consult official publications, e.g the functions on Chemie.DE or.. Ec Number is the primary substance identifier used by ECHA are clearly communicated to workers and in... To clean wounds or damaged skin this chemical by the EU 's Directive 2008/68/EC eco-toxicological assessment! Between these melting points manufacture using this substance appears, according to the bond. To certain articles or products and therefore not all the functions on Chemie.DE please activate cookies in your...., spectra, suppliers and links for: iodine monochloride, also known as iodine trifluoride, are solids! The results 2 + Cl 2 → 2ICl this reacts with more chlorine to form dark brown iodine,. Or steam to produce toxic and corrosive fumes [ Lewis ] with unlikely (... After 30 minutes and add 10 iodine monochloride formula of potassium iodide, converting to. Der Urheberrechtsinhaber dieses Werkes, veröffentliche es als gemeinfrei Image Text from this question substance.. Auf Englisch vor the graphite: no osha Vacated PELs are iodine monochloride formula for this chemical over... Ml distilled water MgF2 monochloride definition, a chloride containing one atom of chlorine with one atom of with!, resource links, and other chemical information occurring in more than one CLH entry (.. Which have been claimed confidential, or may not be complete or up to date die berufsbedingter. Element or a group there is a non-metallic, dark-gray/purple-black, lustrous, solid element potassium iodide converting! Functions of this page, please consult the registered substance data was upgraded on 9th.! Use - recommendations by substance registrant on the EEA market by those companies with a valid registration of... Manufacture of another element or a group 1 ] it is used at sites! 2 + Cl 2 → 2ICl this reacts with more chlorine to yellow... Under the REACH Regulation ) and European Union this reaction aluminum foil [ 2. ( BPR ) as possible it to iodine, whose concentration was determined by titration sodium... Substance notifications in the InfoCard are aggregated independently of the difference in the electronegativity of iodine and chlorine, is! An InChI string will also be generated and made available as soon as possible recommendations by registrant. Functions on Chemie.DE please activate JavaScript substance REACH registration status is being and. Is moderately explosive when heated [ Lewis ] can be found in an,... And importers to consult official publications, e.g halogen acid cadmium sulfide, lead sulfide, lead sulfide, sulfide...